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تسجيل مستخدم جديدAnisotropic Correlated Electronic Structure of Colossal Thermopower Marcasite FeSb$_2$
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Iron antimonide (FeSb$_2$) is a mysterious material with peculiar colossal thermopower of about $-45$ mV/K at 10 K. However, a unified microscopic description of this phenomenon is far from being achieved. The understanding of the electronic structure in details is crucial in identifying the microscopic mechanism of FeSb$_2$ thermopower. Combining angle-resolved photoemission spectroscopy (ARPES) and first-principles calculations we find that the spectrum of FeSb$_2$ consists of two bands near the Fermi energy: the nondispersive strongly renormalized $alpha$-band, and the hole-like $beta$-band that intersects the first one at $Gamma$ and Y points of the Brillouin zone. Our study reveals the presence of sizable correlations, predominantly among electrons derived from Fe-3d states, and considerable anisotropy in the electronic structure of FeSb$_2$. These key ingredients are of fundamental importance in the description of colossal thermopower in FeSb$_2$.
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The iron antimonide FeSb$_2$ possesses an extraordinarily high thermoelectric power factor at low temperature, making it a leading candidate for cryogenic thermoelectric cooling devices. However, the origin of this unusual behavior is controversial,
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