Several well-established benchmark predictors exist for Value-at-Risk (VaR), a major instrument for financial risk management. Hybrid methods combining AR-GARCH filtering with skewed-$t$ residuals and the extreme value theory-based approach are particularly recommended. This study introduces yet another VaR predictor, G-VaR, which follows a novel methodology. Inspired by the recent mathematical theory of sublinear expectation, G-VaR is built upon the concept of model uncertainty, which in the present case signifies that the inherent volatility of financial returns cannot be characterized by a single distribution but rather by infinitely many statistical distributions. By considering the worst scenario among these potential distributions, the G-VaR predictor is precisely identified. Extensive experiments on both the NASDAQ Composite Index and S&P500 Index demonstrate the excellent performance of the G-VaR predictor, which is superior to most existing benchmark VaR predictors.