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تسجيل مستخدم جديدGeneration of Anti-Stokes Fluorescence in a Strongly Coupled Organic Semiconductor Microcavity
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We explore the generation of anti-Stokes fluorescence from strongly coupled organic dye microcavities following resonant ground-state excitation. We observe polariton emission along the lower polariton branch, with our results indicating that this process involves a return to the exciton reservoir and the absorption of thermal energy from molecules in a vibrationally excited ground-state. We speculate that the generation of a population of hot polaritons is enhanced by the fact that the cavity supresses the emission of Stokes-shifted fluorescence, as it is located energetically below the cut-off frequency of the cavity.
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