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Consecutive stochastic 90{deg} polarization switching events, clearly resolved in recent experiments, are described by a new nucleation and growth multi-step model. It extends the classical Kolmogorov-Avrami-Ishibashi approach and includes possible consecutive 90{deg}- and parallel 180{deg}-switching events. The model predicts the results of simultaneous time-resolved macroscopic measurements of polarization and strain, performed on a tetragonal Pb(Zr,Ti)O3 ceramic in a wide range of electric fields over a time domain of five orders of the magnitude. It allows the determination of the fractions of individual switching processes, their characteristic switching times, activation fields, and respective Avrami indices.
A stochastic model for the field-driven polarization reversal in rhombohedral ferroelectrics is developed, providing a description of their temporal electromechanical response. Application of the model to simultaneous measurements of polarization and
A stochastic model of electric field-driven polarization reversal in orthorhombic ferroelectrics is advanced, providing a description of their temporal electromechanical response. The theory accounts for all possible parallel and sequential switching
A stochastic model for polarization switching in tetragonal ferroelectric ceramics is introduced, which includes sequential 90{deg}- and parallel 180{deg}-switching processes and accounts for the dispersion of characteristic switching times due to a
Statistical distribution of switching times is a key information necessary to describe the dynamic response of a polycrystalline bulk ferroelectric to an applied electric field. The Inhomogeneous Field Mechanism (IFM) model offers a useful tool which
In this study, we carry out density functional theory calculations to elucidate the polarization switching mechanism in charge-order-induced ferroelectrics. Based on the investigations about (SrVO$_3$)$_1$(LaVO$_3$)$_1$ superlattice, we demonstrate t