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VO$_2$ is a unique phase change material with strongly anisotropic electronic properties. Recently, samples have been prepared that present a co-existence of phases and thus form metal-insulator junctions of the same chemical compound. Using first principles calculations, the optical properties of metallic and semiconducting VO$_2$ are here discussed to design self-contained natural optical metamaterials, avoiding coupling with other dielectric media. The analysis of the optical properties complements the experiments in the description of the vast change in reflectance and metallicity for both disordered and planar compounds. The present results also predict the possibility to realize ordered VO$_2$ junctions operating as efficient hyperbolic metamaterials in the THz-visible range, by simply adjusting the ratio between metallic and insulating VO$_2$ content. The possibility to excite propagating {em volume plasmom polariton} across the metamaterial is finally discussed.
Raman and combined trasmission and reflectivity mid infrared measurements have been carried out on monoclinic VO$_2$ at room temperature over the 0-19 GPa and 0-14 GPa pressure ranges, respectively. The pressure dependence obtained for both lattice d
Experimentally Cr doping in the rutile phase of VO$_2$ is found to stabilize a charge ordered ferromagnetic insulating state in the doping range of 10% to 20%. In this work, we investigated its origin at 12.5% Cr doping using a combination of ab-init
In this work we present a comparative investigation of the electronic structures of NbO$_2$ and VO$_2$ obtained within the combination of density functional theory and cluster-dynamical mean field theory calculations. We investigate the role of dynam
Rutile ($R$) phase VO$_2$ is a quintessential example of a strongly correlated bad-metal, which undergoes a metal-insulator transition (MIT) concomitant with a structural transition to a V-V dimerized monoclinic phase below T$_{MIT} sim 340K$. It has
The layered crystal of EuSn$_2$As$_2$ has a Bi$_2$Te$_3$-type structure in rhombohedral ($Rbar{3}m$) symmetry and has been confirmed to be an intrinsic magnetic topological insulator at ambient conditions. Combining {it ab initio} calculations and em