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Fermis golden rule applies to a situation in which a single quantum state $|psirangle$ is coupled to a near-continuum. This quasi-continuum coupling structure results in a rate equation for the population of $|psirangle$. Here we show that the coupling of a quantum system to the standard model of a thermal environment, a bath of harmonic oscillators, can be decomposed into a cascade made up of the quasi-continuum coupling structures of Fermis golden rule. This clarifies the connection between the physics of the golden rule and that of a thermal bath, and provides a non-rigorous but physically intuitive derivation of the Markovian master equation directly from the former. The exact solution to the Hamiltonian of the golden rule, known as the Bixon-Jortner model, generalized for an asymmetric spectrum, provides a window on how the evolution induced by the bath deviates from the master equation as one moves outside the Markovian regime. Our analysis also reveals the relationship between the oscillator bath and the random matrix model (RMT) of a thermal bath. We show that the cascade structure is the one essential difference between the two models, and the lack of it prevents the RMT from generating transition rates that are independent of the initial state of the system. We suggest that the cascade structure is one of the generic elements of thermalizing many-body systems.
Fermis golden rule is of great importance in quantum dynamics. However, in many textbooks on quantum mechanics, its contents and limitations are obscured by the approximations and arguments in the derivation, which are inevitable because of the gener
A study is made of the behavior of unstable states in simple models which nevertheless are realistic representations of situations occurring in nature. It is demonstrated that a non-exponential decay pattern will ultimately dominate decay due to a lo
Fermis golden rule defines the transition rate between weakly coupled states and can thus be used to describe a multitude of molecular processes including electron-transfer reactions and light-matter interaction. However, it can only be calculated if
We discuss the decay of unstable states into a quasicontinuum using models of the effective Hamiltonian type. The goal is to show that exponential decay and the golden rule are exact in a suitable scaling limit, and that there is an associated renorm
Time evolution of a harmonic oscillator linearly coupled to a heat bath is compared for three classes of initial states for the bath modes - grand canonical ensemble, number states and coherent states. It is shown that for a wide class of number stat