The spinodal instabilities in hot asymmetric nuclear matter and some important critical parameters derived thereof are studied using six different families of relativistic mean-field (RMF) models. The slopes of the symmetry energy coefficient vary over a wide range within each family. The critical densities and proton fractions are more sensitive to the symmetry energy slope parameter at temperatures much below its critical value ($T_csim$14-16 MeV). The spread in the critical proton fraction at a given symmetry energy slope parameter is noticeably larger near $T_c$, indicating that the warm equation of state of asymmetric nuclear matter at sub-saturation densities is not sufficiently constrained. The distillation effects are sensitive to the density dependence of the symmetry energy at low temperatures which tend to wash out with increasing temperature.