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We report the discovery and characterization of a novel 112-type iron pnictide EuFeAs2, with La-doping induced superconductivity in a series of Eu1-xLaxFeAs2. The polycrystalline samples were synthesized through solid state reaction method only within a very narrow temperature window around 1073 K. Small single crystals were also grown from a flux method with the size about 100 um. The crystal structure was identified by single crystal X-ray diffraction analysis as a monoclinic structure with space group of P21/m. From resistivity and magnetic susceptibility measurements, we found that the parent compound EuFeAs2 shows a Fe2+ related antiferromagnetic/structural phase transition near 110 K and a Eu2+ related antiferromagnetic phase transition near 40 K. La doping suppressed the both phase transitions and induced superconducting transition with a Tc ~ 11 K for Eu0.85La0.15FeAs2.
The effects of pressure on antiferromagnetic (AFM) and superconducting phase transitions of 112-type Ca$_{1-x}$La$_{x}$FeAs$_{2}$ were studied, and the in-plane electrical resistivity $rho_{ab}$ was measured with an indenter-type pressure cell. The A
We use neutron powder diffraction to study on the non-superconducting phases of ThFeAsN$_{1-x}$O$_x$ with $x=0.15, 0.6$. In our previous results on the superconducting phase ThFeAsN with $T_c=$ 30 K, no magnetic transition is observed by cooling down
The solid solution of antimonide-oxides Ba1-xKxTi2Sb2O (0 < x < 1) has been synthesized by solid-state reactions and characterized by X-ray powder diffraction (CeCr2Si2C-type structure; P4/mmm, Z = 1). The crystal structure consists of Ti2Sb2O-layers
We use inelastic neutron scattering to study the low-energy spin excitations of 112-type iron pnictide Ca$_{0.82}$La$_{0.18}$Fe$_{0.96}$Ni$_{0.04}$As$_{2}$ with bulk superconductivity below $T_c=22$ K. A two-dimensional spin resonance mode is found a
Here we report the discovery of the first ternary molybdenum pnictide based superconductor K2Mo3As3. Polycrystalline samples were synthesized by the conventional solid state reaction method. X-ray diffraction analysis reveals a quasi-one-dimensional