Using Chandra ACIS-S, we have obtained imaging Xray spectrophotometry of the Pluto system in support of the New Horizons flyby on 14 July 2015. 174 ksec of observations were obtained on 4 visits in Feb 2014 to Aug 2015. We measured a net signal of 6.8 counts and a noise level of 1.2 counts in a comoving 11 x 11 pixel box (100 x 100 R_Pluto) in the 0.31 to 0.60 keV passband for a detection at > 99.95 C.L. The Pluto photons do not match the background spectrum, are coincident with a 90% flux aperture comoving with Pluto, and are not sky source confused. The mean 0.31 to 0.60 keV Xray power from Pluto is 200 MW, in the midrange of Xray power levels seen for known solar system emission sources: auroral precipitation, solar Xray scattering, and charge exchange (CXE) between solar wind (SW) ions & atmospheric neutrals. We eliminate auroral effects as a source, as Pluto has no known magnetic field & the New Horizons Alice UV spectrometer detected no airglow from Pluto during the flyby. Nano-scale atmospheric haze particles could lead to enhanced resonant scattering of solar X-rays from Pluto, but the energy signature of the detected photons does not match the solar spectrum and estimates of Plutos scattered Xray emission are > 100 times below the 3.9e-5 cps found in our observations. CXE emission from SW carbon, nitrogen, and oxygen ions can produce the energy signature seen, and the 6e25 neutral gas escape rate from Pluto deduced from New Horizons data can support the 3.0e24 Xray photons/sec emission rate required by our observations. Using the SW proton density and speed measured by the Solar Wind Around Pluto (SWAP) instrument in the vicinity of Pluto at the time of the photon emissions, we find too few SW minor ions flowing into the 11 x 11 pixel box centered on Pluto than are needed to support the observed emission rate unless the SW is significantly focused and enhanced in this region.
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