The conversion of the IR emission into star formation rate can be strongly dependent on the physical properties of the dust, which are affected by the environmental conditions where the dust is embedded. We study here the dust properties of a set of HII regions in the Local Group Galaxy M33 presenting different spatial configurations between the stars, gas and dust to understand the dust evolution under different environments. We model the SED of each region using the DustEM tool and obtain the mass relative to hydrogen for Very Small Grains (YVSG), Polycyclic Aromatic Hydrocarbons (YPAH) and Big Grains (YBG). The relative mass of the VSGs (YVSG/YTOT) is a factor of 1.7 higher for HII regions classified as filled and mixed than for regions presenting a shell structure. The enhancement of VSGs within NGC 604 and NGC 595 is correlated to expansive gas structures with velocities greater than 50 km/s. The gas-to-dust ratio derived for the HII regions in our sample exhibits two regimes related to the HI-H2 transition of the ISM. Regions corresponding to the HI diffuse regime present a gas-to-dust ratio compatible with the expected value if we assume that the gas-to-dust ratio scales linearly with metallicity, while regions corresponding to a H2 molecular phase present a flatter dust-gas surface density distribution. The fraction of VSGs can be affected by the conditions of the interstellar environment: strong shocks of 50-90 km/s existing in the interior of the most luminous HII regions can lead to fragmentation of BGs into smaller ones, while the more evolved shell and clear shell objects provide a more quiescent environment where reformation of dust BG grains might occur. The gas-to-dust variations found in this analysis might imply that grain coagulation and/or gas-phase metals incorporation to the dust mass is occurring in the interior of the HII regions in M33.
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