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High degrees of deuterium fractionation are commonly found in cold prestellar cores and in the envelopes around young protostars. As it brings strong constraints to chemical models, deuterium chemistry is often used to infer core history or molecule formation pathways. Whereas a large number of observations is available regarding interstellar deuterated stable molecules, relatively little is known about the deuteration of hydride radicals, as their fundamental rotational transitions are at high frequencies where the atmosphere is mostly opaque. Nitrogen hydride radicals are important species in nitrogen chemistry, as they are thought to be related to ammonia formation. Observations have shown that ammonia is strongly deuterated, with [NH2D]/[NH3] ~ 10%. Models predict similarly high [ND]/[NH] ratios, but so far only one observational determination of this ratio is available, towards the envelope of the protostar IRAS16293-2422. In order to test model predictions, we aim here at determining [ND]/[NH] in a dense, starless core. We observed NH and ND in 16293E with the HIFI spectrometer on board the Herschel Space Observatory as part of the CHESS guaranteed time key programme, and derived the abundances of these two species using a non-LTE non-local radiative transfer model. Both NH and ND are detected in the source, with ND in emission and NH in absorption against the continuum arising from the cold dust emission. Our model shows however that the ND emission and the NH absorption originate from different layers in the cloud, as further evidenced by their different velocities. In the central region of the core, we can set a lower limit to the [ND]/[NH] ratio of ~2%. This estimate is consistent with recent pure gas-phase models of nitrogen chemistry
We present Herschel, ALMA Compact Array (ACA), and Caltech Submillimeter Observatory (CSO) observations of the prestellar core in L1689N, which has been suggested to be interacting with a molecular outflow driven by the nearby solar type protostar IR
Context: In the last years, the H2D+ and D2H+ molecules have gained great attention as probes of cold and depleted dense molecular cloud cores. These ions are at the basis of molecular deuterium fractionation, a common characteristic observed in star
Complex organic molecules (COMs) are detected in many regions of the interstellar medium, including prestellar cores. However, their formation mechanisms in cold (~10 K) cores remain to this date poorly understood. The formyl radical HCO is an import
Aims. To constrain the physical processes that lead to the birth of high-mass stars it is mandatory to study the very first stages of their formation. We search for high-mass analogs of low-mass prestellar cores in W43-MM1. Methods. We conducted a
Exploring the structure and dynamics of cold starless clouds is necessary to understand the different steps leading to the formation of protostars. Because clouds evolve slowly, many of them must be studied in detail to pick up different moments of a