Spectroscopy of divalent rare earth ions in fluoride crystals


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We have studied the absorption spectra of x-ray irradiation-induced Ce2+ and Pr2+ ions in crystals of alkaline-earth fluorides. We have calculated absorption spectra of divalent praseodymium ions in SrF2 crystals doped with Pr2+ for the first time. The calculated spectra agree rather well with the experimental data. In crystals containing induced Ce2+ ions we have found strong electron-phonon coupling. In BaF2, we do not observe bands corresponded to divalent Ce or Pr ions.

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