By looking at the kinetic Sunyaev-Zeldovich effect (kSZ) in Planck nominal mission data, we present a significant detection of baryons participating in large-scale bulk flows around central galaxies (CGs) at redshift $zapprox 0.1$. We estimate the pairwise momentum of the kSZ temperature fluctuations at the positions of the CGC (Central Galaxy Catalogue) samples extracted from Sloan Digital Sky Survey (DR7) data. For the foreground-cleaned maps, we find $1.8$-$2.5sigma$ detections of the kSZ signal, which are consistent with the kSZ evidence found in individual Planck raw frequency maps, although lower than found in the WMAP-9yr W band ($3.3sigma$). We further reconstruct the peculiar velocity field from the CG density field, and compute for the first time the cross-correlation function between kSZ temperature fluctuations and estimates of CG radial peculiar velocities. This correlation function yields a $3.0$-$3.7$$sigma$ detection of the peculiar motion of extended gas on Mpc scales, in flows correlated up to distances of 80-100 $h^{-1}$ Mpc. Both the pairwise momentum estimates and kSZ temperature-velocity field correlation find evidence for kSZ signatures out to apertures of 8 arcmin and beyond, corresponding to a physical radius of $> 1$ Mpc, more than twice the mean virial radius of halos. This is consistent with the predictions from hydro simulations that most of the baryons are outside the virialized halos. We fit a simple model, in which the temperature-velocity cross-correlation is proportional to the signal seen in a semi-analytic model built upon N-body simulations, and interpret the proportionality constant as an effective optical depth to Thomson scattering. We find $tau_T=(1.4pm0.5)times 10^{-4}$; the simplest interpretation of this measurement is that much of the gas is in a diffuse phase, which contributes little signal to X-ray or thermal SZ observations.