Ap Lib is one of the rare Low Synchrotron Peaked blazars detected so far at TeV energies. This type of source is not properly modelled by standard one-zone leptonic Synchrotron-self-Compton (SSC) emission scenarios. The aim of this paper is to study the relevance of additional components which should naturally occur in a SSC scenario for a better understanding of the emission mechanisms, especially at very high energies (VHE). Methods. We use simultaneous data from a multi-wavelength campaign of Planck, Swift-UVOT and Swift-XRT telescopes carried out in February 2010, as well as quasi-simultaneous data of WISE, Fermi and H.E.S.S. taken in 2010. The multi-lambda emission of Ap Lib is modelled by a blob-in-jet SSC scenario including the contribution of the base of the VLBI extended jet, the radiative blob-jet interaction, the accretion disk and its associated external photon field. We show that signatures of a strong parsec-scale jet and of an accretion disk emission are present in the SED. We can link the observationnal VLBI jet features from MOJAVE to parameters expected for a VHE emitting blob accelerated near the jet base. The VHE emission appears to be dominated by the inverse-Compton effect of the blob relativistic electrons interacting with the jet synchrotron radiation. In such scenario Ap Lib appears as an intermediate source between BL Lac objects and Flat Spectrum Radio Quasars. Ap Lib could be a bright representative of a specific class of blazars, in which the parsec-scale jet luminosity is no more negligible compared to the blob and contributes to the high energy emission via inverse Compton processes.