Here we study the structure of a highly ionizing shock wave in a gas of high atmospheric pressure. We take into account the gas ionization when the gas temperature reaches few orders of an ionization potential. It is shown that after gasdynamic temperature-raising shock and formation of a highly-ionized nonisothermal plasma $T_e>>T_i$ only the solitary ion-sound wave (soliton) can propagate in this plasma. In such a wave the charge separation occurs: electrons and ions form the double electric layer with the electric field. The shock wave form, its amplitude and front width are obtained.