اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدElectron configuration of the substitutional nitrogen defect in diamond
167
0
0.0
(
0
)
تأليف
Jozsef Garai
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
It is suggested that the substitutional nitrogen in diamonds bonded to three of the surrounding carbon atoms instead of four. This proposed electron configuration of the defect is deduced from previous experiments and theoretical considerations. Notably, the 1344 cm-1 band, characteristics of the substitutional Nitrogen, is independent of the isotopic change of Nitrogen but depend on the isotopic change of Carbon. The well established NV centre should not be stable if Nitrogen is bounded to four of the surrounding Carbon. Additional support comes from the substantially bigger size of the single substitutional nitrogen atom indicating loan pair electron. The proposed configuration of the substitutional Nitrogen was also tested by using a simple force constant model. Replacing force constant of C-N with 2/3 C-C:1/3 C=C reproduces the 1344 cm-1 band.
قيم البحث
اقرأ أيضاً
Photochromism in single nitrogen-vacancy optical centers in diamond is demonstrated. Time-resolved optical spectroscopy shows that intense irradiation at 514 nm switches the nitrogen-vacancy defects to the negative form. This defect state relaxes bac
k to the neutral form under dark conditions. Temporal anticorrelation of photons emitted by the different charge states of the optical center unambiguously indicates that the nitrogen-vacancy defect accounts for both 575 nm and 638 nm emission bands. Possible mechanism of photochromism involving nitrogen donors is discussed.
Fluorescent nanodiamonds containing negatively-charged nitrogen-vacancy (NV$^-$) centers are promising for a wide range of applications, such as for sensing, as fluorescence biomarkers, or to hyperpolarize nuclear spins. NV$^-$ centers are formed fro
m substitutional nitrogen (P1 centers) defects and vacancies in the diamond lattice. Maximizing the concentration of NVs is most beneficial, which justifies the search for methods with a high yield of conversion from P1 to NV$^-$. We report here the characterization of surface cleaned fluorescent micro- and nanodiamonds, obtained by irradiation of commercial diamond powder with high-energy (10 MeV) electrons and simultaneous annealing at 800{deg}C. Using this technique and increasing the irradiation dose, we demonstrate the creation of NV$^-$ with up to 25 % conversion yield. Finally, we monitor the creation of irradiation-induced spin-1 defects in microdiamond particles, which we associate with W16 and W33 centers, and investigate the effects of irradiation dose and particle size on the coherence time of NV$^-$.
We have quantified substitutional impurity concentrations in synthetic diamond crystals down to sub parts-per-billion levels. The capture lifetimes of electrons and excitons injected by photoexcitation were compared for several samples with different
impurity concentrations. Based on the assessed impurity concentrations, we have determined the capture cross section of electrons to boron impurity, sA=1.3x10^-14 cm2, and that of excitons to nitrogen impurity, sD^ex=3.1x10^-14 cm2. The general tendency of the mobility values for different carrier species is successfully reproduced by including carrier scattering by impurities and by excitons.
The nitrogen-vacancy (NV) colour centre in diamond is an important physical system for emergent quantum technologies, including quantum metrology, information processing and communications, as well as for various nanotechnologies, such as biological
and sub-diffraction limit imaging, and for tests of entanglement in quantum mechanics. Given this array of existing and potential applications and the almost 50 years of NV research, one would expect that the physics of the centre is well understood, however, the study of the NV centre has proved challenging, with many early assertions now believed false and many remaining issues yet to be resolved. This review represents the first time that the key empirical and ab initio results have been extracted from the extensive NV literature and assembled into one consistent picture of the current understanding of the centre. As a result, the key unresolved issues concerning the NV centre are identified and the possible avenues for their resolution are examined.
Symmetry considerations are used in presenting a model of the electronic structure and the associated dynamics of the nitrogen-vacancy center in diamond. The model accounts for the occurrence of optically induced spin polarization, for the change of
emission level with spin polarization and for new measurements of transient emission. The rate constants given are in variance to those reported previously.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
