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We undertook a mutually complementary analytic and computational study of the full-fledged spherical (3D) quantum rotor subject to combined orienting and aligning interactions characterized, respectively, by dimensionless parameters $eta$ and $zeta$. By making use of supersymmetric quantum mechanics (SUSY QM), we found two sets of conditions under which the problem of a spherical quantum pendulum becomes analytically solvable. These conditions coincide with the loci $zeta=frac{eta^2}{4k^2}$ of the intersections of the eigenenergy surfaces spanned by the $eta$ and $zeta$ parameters. The integer topological index $k$ is independent of the eigenstate and thus of the projection quantum number $m$. These findings have repercussions for rotational spectra and dynamics of molecules subject to combined permanent and induced dipole interactions.
We make use of supersymmetric quantum mechanics (SUSY QM) to find three sets of conditions under which the problem of a planar quantum pendulum becomes analytically solvable. The analytic forms of the pendulums eigenfuntions make it possible to find
Recently, we have theoretically proposed and experimentally demonstrated an exact and efficient quantum simulation of photosynthetic light harvesting in nuclear magnetic resonance (NMR), cf. B. X. Wang, textit{et al.} npj Quantum Inf.~textbf{4}, 52 (
An anharmonic oscillator when driven with a fast, frequency chirped voltage pulse can oscillate with either small or large amplitude depending on whether the drive voltage is below or above a critical value-a well studied classical phenomenon known a
Molecules are the most demanding quantum systems to be simulated by quantum computers because of their complexity and the emergent role of quantum nature. The recent theoretical proposal of Huh et al. (Nature Photon., 9, 615 (2015)) showed that a mul
We study coherent superpositions of clockwise and anti-clockwise rotating intermediate complexes with overlapping resonances formed in bimolecular chemical reactions. Disintegration of such complexes represents an analog of famous double-slit experim