We study the minimal unitary representation (minrep) of SO(5,2), obtained by quantization of its geometric quasiconformal action, its deformations and supersymmetric extensions. The minrep of SO(5,2) describes a massless conformal scalar field in five dimensions and admits a unique deformation which describes a massless conformal spinor. Scalar and spinor minreps of SO(5,2) are the 5d analogs of Diracs singletons of SO(3,2). We then construct the minimal unitary representation of the unique 5d superconformal algebra F(4) with the even subalgebra SO(5,2) X SU(2). The minrep of F(4) describes a massless conformal supermultiplet consisting of two scalar and one spinor fields. We then extend our results to the construction of higher spin AdS_6/CFT_5 (super)-algebras. The Joseph ideal of the minrep of SO(5,2) vanishes identically as operators and hence its enveloping algebra yields the AdS_6/CFT_5 bosonic higher spin algebra directly. The enveloping algebra of the spinor minrep defines a deformed higher spin algebra for which a deformed Joseph ideal vanishes identically as operators. These results are then extended to the construction of the unique higher spin AdS_6/CFT_5 superalgebra as the enveloping algebra of the minimal unitary realization of F(4) obtained by the quasiconformal methods.
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