اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدNeutron activation analysis of the 30Si content of highly enriched 28Si: proof of concept and estimation of the achievable uncertainty
85
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
We investigated the use of neutron activation to estimate the 30Si mole fraction of the ultra-pure silicon material highly enriched in 28Si for the measurement of the Avogadro constant. Specifically, we developed a relative method based on Instrumental Neutron Activation Analysis and using a natural-Si sample as a standard. To evaluate the achievable uncertainty, we irradiated a 6 g sample of a natural-Si material and modeled experimentally the signal that would be produced by a sample of the 28Si-enriched material of similar mass and subjected to the same measurement conditions. The extrapolation of the expected uncertainty from the experimental data indicates that a measurement of the 30Si mole fraction of the 28Si-enriched material might reach a 4% relative combined standard uncertainty.
قيم البحث
اقرأ أيضاً
The determination of the Avogadro constant plays a key role in the redefinition of the kilogram in terms of a fundamental constant. The present experiment makes use of a silicon single-crystal highly enriched in 28Si that must have a total impurity m
ass fraction smaller than a few parts in 109. To verify this requirement, we previously developed a relative analytical method based on neutron activation for the elemental characterization of a sample of the precursor natural silicon crystal WASO 04. The method is now extended to fifty-nine elements and applied to a monoisotopic 28Si single-crystal that was grown to test the achievable enrichment. Since this crystal was likely contaminated, this measurement tested also the detection capabilities of the analysis. The results quantified contaminations by Ge, Ga, As, Tm, Lu, Ta, W and Ir and, for a number of the detectable elements, demonstrated that we can already reach the targeted 1 ng/g detection limit.
The latest determination of the Avogadro constant, carried out by counting the atoms in a pure silicon crystal highly enriched in 28Si, reached the target 2x10-8 relative uncertainty required for the redefinition of the kilogram based on the Planck c
onstant. The knowledge of the isotopic composition of the enriched silicon material is central; it is measured by isotope dilution mass spectrometry. In this work, an independent estimate of the 30Si mole fraction was obtained by applying a relative measurement protocol based on Instrumental Neutron Activation Analysis. The amount of 30Si isotope was determined by counting the 1266.1 keV gamma-photons emitted during the radioactive decay of the radioisotope 31Si produced via the neutron capture reaction 30Si(n,gamma)31Si. The x(30Si) = 1.043(19)x10-6 mol mol-1 is consistent with the value currently adopted by the International Avogadro Coordination.
The results of analytical measurements performed with solid-sampling techniques are affected by the distribution of the analytes within the matrix. The effect becomes significant in case of determination of trace elements in small subsamples. In this
framework we propose a measurement model based on Instrumental Neutron Activation Analysis to determine the relative variability of the amount of an analyte among subsamples of a material. The measurement uncertainty is evaluated and includes the counting statistics, the full-energy gamma peak efficiency and the spatial gradient of the neutron flux at the irradiation position. The data we obtained in a neutron activation experiment and showing the relative variability of As, Au, Ir, Sb and W among subsamples of a highly pure Rh foil are also presented.
An imaging technique with sensitivity to short duration optical transients is described. The technique is based on the use of wide-field cameras operating in a drift scanning mode, whereby persistent objects produce trails on the sensor and short dur
ation transients occupy localised groups of pixels. A benefit of the technique is that sensitivity to short duration signals is not accompanied by massive data rates, because the exposure time >> transient duration. The technique is demonstrated using a pre-prototype system composed of readily available and inexpensive commercial components, coupled with common coding environments, commercially available software, and free web-based services. The performance of the technique and the pre-prototype system is explored, including aspects of photometric and astrometric calibration, detection sensitivity, characterisation of candidate transients, and the differentiation of astronomical signals from non-astronomical signals (primarily glints from satellites in Earth orbit and cosmic ray hits on sensor pixels). Test observations were made using the pre-prototype system, achieving sensitivity to transients with 21 ms duration, resulting in the detection of five candidate transients. An investigation of these candidates concludes they are most likely due to cosmic ray hits on the sensor and/or satellites. The sensitivity obtained with the pre-prototype system is such that, under some models for the optical emission from FRBs, the detection of a typical FRB, such as FRB181228, to a distance of approximately 100 Mpc is plausible. Several options for improving the system/technique in the future are described.
Neutrino physics is nowadays receiving more and more attention as a possible source of information for the long-standing problem of new physics beyond the Standard Model. The recent measurement of the third mixing angle theta13 in the standard mixing
oscillation scenario encourages us to pursue the still missing results on leptonic CP violation and absolute neutrino masses. However, several puzzling measurements exist, which deserve an exhaustive evaluation. The NESSiE Collaboration has been setup to undertake a definitive experiment to clarify the muon disappearance measurements at small L/E, which will be able to put severe constraints to any model with more than the three-standard neutrinos, or even to robustly measure the presence of a new kind of neutrino oscillation for the first time. Within the context of the current CERN project, aimed to revitalize the neutrino field in Europe, we will illustrate the achievements that can be obtained by a double muon-spectrometer system, with emphasis on the search for sterile neutrinos.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
