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We present Herschel/HIFI observations of the light hydride H$_{2}$S obtained from the full spectral scan of the Orion Kleinmann-Low nebula (Orion KL) taken as part of the HEXOS GT key program. In total, we observe 52, 24, and 8 unblended or slightly blended features from H$_{2}$$^{32}$S, H$_{2}$$^{34}$S, and H$_{2}$$^{33}$S, respectively. We only analyze emission from the so called hot core, but emission from the plateau, extended ridge, and/or compact ridge are also detected. Rotation diagrams for ortho and para H$_{2}$S follow straight lines given the uncertainties and yield T$_{rm rot}$=141$pm$12 K. This indicates H$_{2}$S is in LTE and is well characterized by a single kinetic temperature or an intense far-IR radiation field is redistributing the population to produce the observed trend. We argue the latter scenario is more probable and find that the most highly excited states (E$_{rm up}$>1000 K) are likely populated primarily by radiation pumping. We derive an H$_{2}$$^{32}$S column density, N$_{rm tot}$(H$_{2}$$^{32}$S)=9.5$pm$1.9$times$10$^{17}$ cm$^{-2}$, gas kinetic temperature, T$_{rm kin}$=120$pm^{13}_{10}$ K, and constrain the H$_{2}$ volume density, n$_{H2}$>9$times$10$^{7}$ cm$^{-3}$, for the H$_{2}$S emitting gas. These results point to an H$_{2}$S origin in markedly dense, heavily embedded gas, possibly in close proximity to a hidden self-luminous source (or sources), which are conceivably responsible for Orion KLs high luminosity. We also derive an H$_{2}$S ortho/para ratio of 1.7$pm$0.8 and set an upper limit for HDS/H2S of <4.9$times$10$^{-3}$.
We have examined methanol emission from Orion KL with of the {em Herschel}/HIFI instrument, and detected two methanol bands centered at 524 GHz and 1061 GHz. The 524 GHz methanol band (observed in HIFI band 1a) is dominated by the isolated $Delta$J$=
We report the detection of more than 48 velocity-resolved ground rotational state transitions of H2(16)O, H2(18)O, and H2(17)O - most for the first time - in both emission and absorption toward Orion KL using Herschel/HIFI. We show that a simple fit,
We report a detection of the fundamental rotational transition of hydrogen fluoride in absorption towards Orion KL using Herschel/HIFI. After the removal of contaminating features associated with common molecules (weeds), the HF spectrum shows a P-Cy
We present a comprehensive analysis of a broad band spectral line survey of the Orion Kleinmann-Low nebula (Orion KL), one of the most chemically rich regions in the Galaxy, using the HIFI instrument on board the Herschel Space Observatory. This surv
We present chemical implications arising from spectral models fit to the Herschel/HIFI spectral survey toward the Orion Kleinmann-Low nebula (Orion KL). We focus our discussion on the eight complex organics detected within the HIFI survey utilizing a