اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدComplex magnetic behavior of the sawtooth Fe chains in Rb$_{2}$Fe$_{2}$O(AsO$_{4}$)$_{2}$
223
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
Results of magnetic field and temperature dependent neutron diffraction and magnetization measurements on oxy-arsenate Rb$_{2}$Fe$_{2}$O(AsO$_{4}$)$_{2}$ are reported. The crystal structure of this compound contains pseudo-one-dimensional [Fe$_{2}$O$_{6}$]$^infty$ sawtooth-like chains, formed by corner sharing isosceles triangles of $Fe^{3+}$ ions occupying two nonequivalent crystallographic sites. The chains extend infinitely along the crystallographic $b$-axis and are structurally confined from one another via diamagnetic (AsO$_{4}$)$^{3-}$ units along the $a$-axis, and Rb$^+$ cations along the $c$-axis direction. Neutron diffraction measurements indicate the onset of a long range antiferromagnetic order below approximately 25 K. The magnetic structure consists of ferrimagnetic chains which are antiferromagnetically coupled with each other. Within each chain, one of the two Fe sites carries a moment which lies along the emph{b}-axis, while the second site bears a canted moment in the opposite direction. Externally applied magnetic field induces a transition to a ferrimagnetic state, in which the coupling between the sawtooth chains becomes ferromagnetic. Magnetization measurements performed on optically-aligned single crystals reveal evidence for an uncompensated magnetization at low magnetic fields that could emerge from to a phase-segregated state with ferrimagnetic inclusions or from antiferromagnetic domain walls. The observed magnetic states and the competition between them is expected to arise from strongly frustrated interactions within the sawtooth chains and relatively weak coupling between them.
قيم البحث
اقرأ أيضاً
We present the results of structural and magnetic phase comparisons of the iron oxychalcogenides La$_{2}$O$_{2}$Fe$_{2}$O$M$$_{2}$ ($M$ = S, Se). Elastic neutron scattering reveals that $M$ = S and Se have similar nuclear structures at room and low t
emperatures. We find that both materials obtain antiferromagnetic ordering at a Neel temperature $T_{N}$ 90.1 $pm$ 0.16 K and 107.2 $pm$ 0.06 K for $M$= Se and S, respectively. The magnetic arrangements of $M$ = S, Se are obtained through Rietveld refinement. We find the order parameter exponent $beta$ to be 0.129 $pm$ 0.006 for $M$ = Se and 0.133 $pm$ 0.007 for $M$ = S. Each of these values is near the Ising symmetry value of 1/8. This suggests that although lattice and electronic structural modifications result from chalcogen exchange, the nature of the magnetic interactions is similar in these materials.
We report on the magnetic, thermodynamic, dielectric, and pyroelectric measurements on the hitherto unreported Fe${_4}$Ta${_2}$O${_9}$. This system is seen to exhibit a series of magnetic transitions, many of which are coupled to the emergence of fer
roelectric order, making Fe${_4}$Ta${_2}$O${_9}$ the only genuine multiferroic in its material class. We suggest that the observed properties arise as a consequence of an effective reduction in the dimensionality of the magnetic lattice, with the magnetically active Fe${^{2+}}$ ions preferentially occupying a quasi 2D buckled honeycomb structure. The low temperature $H$-$T$ phase diagram of Fe${_4}$Ta${_2}$O${_9}$ reveals a rich variety of coupled magnetic and ferroelectric phases, in similarity with that observed in the distorted Kagome systems.
We describe the local structural properties of the iron oxychalcogenides, La$_2$O$_2$Fe$_2$O$M_2$ ($M$ = S, Se), by using pair distribution function (PDF) analysis applied to total scattering data. Our results of neutron powder diffraction show that
$M$ = S and Se possess similar nuclear structure at low and room temperatures. The local crystal structures were studied by investigating deviations in atomic positions and the extent of the formation of orthorhombicity. Analysis of the total scattering data suggests that buckling of the Fe$_2$O plane occurs below 100 K. The buckling may occur concomitantly with a change in octahedral height. Furthermore, within a typical range of 1-2 nm, we observed short-range orthorhombic-like structure suggestive of nematic fluctuations in both of these materials.
The discovery of FeO$_{2}$ containing more oxygen than hematite (Fe$_{2}$O$_{3}$) that was previously believed to be the most oxygen rich iron compounds, has important implications on the study of the deep lower mantle compositions. Compared to other
iron compounds, there are limited reports on FeO$_{2}$ making studies of its physical properties of great interest in fundamental condensed matter physics and geoscience. Even the oxidation state of Fe in FeO$_{2}$ is the subject of debate in theoretical works and there have not been reports from experimental electronic and magnetic properties measurements. Here, we report the pressure-induced spin state transition from synchrotron experiments and our computational results explain the underlying mechanism. Using density functional theory and dynamical mean field theory, we calculated spin states of Fe with volume and Hubbard interaction $U$ change, which clearly demonstrate that Fe in FeO$_{2}$ consists of Fe(II) and peroxide O$_{2}^{2-}$. Our study suggests that localized nature of both Fe 3$d$ orbitals and O$_{2}$ molecular orbitals should be correctly treated for unveiling the structural and electronic properties of FeO$_{2}$.
The study of universal critical behavior is a crucial issue in a continuous phase transition, which groups various critical phenomena into universality classes for revealing microscopic electronic behaviors. The understanding of the nature of magneti
sm in Eu-based ferromagnetic superconductors is largely impeded by the infeasibility of performing inelastic neutron scattering measurements to deduce the microscopic magnetic behaviors and the effects on the superconductivity, due to the significant neutron absorption effect of natural $^{152}$Eu and unavailability of large single crystals. However, by systematically combining the neutron diffraction experiment, the first-principles calculations, and the quantum Monte Carlo simulations, we have obtained a perfectly consistent universal critical exponent value of $beta=0.385(13)$ experimentally and theoretically for Eu(Fe$_{0.75}$Ru$_{0.25}$)$_{2}$As$_{2}$, from which the magnetism in the Eu-based ferromagnetic superconductors is identified as the universal class of a three-dimensional anisotropic quantum Heisenberg model with long-range magnetic exchange coupling. This study not only clarifies the nature of microscopic magnetic behaviors in the Eu-based ferromagnetic superconductors, but also opens a new avenue of systemic methodology for studying the universal critical behaviors associated with magnetic phase transitions in the area of magnetism and the spin fluctuations effects on the unconventional superconductivity.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
