We analyse the large-scale angular correlation function (ACF) of the CMASS luminous galaxies (LGs), a photometric-redshift catalogue based on the Data Release 8 (DR8) of the Sloan Digital Sky Survey-III. This catalogue contains over $600 , , 000$ LGs in the range $0.45 leq z leq 0.65$, which was split into four redshift shells of constant width. First, we estimate the constraints on the redshift-space distortion (RSD) parameters $bsigma_8$ and $fsigma_8$, where $b$ is the galaxy bias, $f$ the growth rate and $sigma_8$ is the normalization of the perturbations, finding that they vary appreciably among different redshift shells, in agreement with previous results using DR7 data. When assuming constant RSD parameters over the survey redshift range, we obtain $fsigma_8 = 0.69 pm 0.21$, which agrees at the $1.5sigma$ level with Baryon Oscillation Spectroscopic Survey DR9 spectroscopic results. Next, we performed two cosmological analyses, where relevant parameters not fitted were kept fixed at their fiducial values. In the first analysis, we extracted the baryon acoustic oscillation peak position for the four redshift shells, and combined with the sound horizon scale from 7-year textit{Wilkinson Microwave Anisotropy Probe} $(WMAP7)$ to produce the constraints $Omega_{m}=0.249 pm 0.031$ and $w=-0.885 pm 0.145$. In the second analysis, we used the ACF full shape information to constrain cosmology using real data for the first time, finding $Omega_{m} = 0.280 pm 0.022$ and $f_b = Omega_b/Omega_m = 0.211 pm 0.026$. These results are in good agreement with $WMAP7$ findings, showing that the ACF can be efficiently applied to constrain cosmology in future photometric galaxy surveys.