Anomalous Diffuse Interstellar Bands in the Spectrum of Herschel 36. II. Analysis of Radiatively Excited CH+, CH, and DIBs

Absorption spectra toward Herschel 36 for the A^1Pi <-- X^1Sigma transitions of CH+ in the J=1 excited rotational level and the A^2Delta <-- X^2Pi transition of CH in the J=3/2 excited fine structure level have been analyzed. These excited levels are above their ground levels by 40.1 K and ~25.7 K and indicate high radiative temperatures of the environment, 14.6 K and 6.7 K, respectively. The effect of the high radiative temperature is more spectacular in some diffuse interstellar bands (DIBs) observed toward Her 36; remarkable extended tails toward red (ETR) were observed. We interpret these ETRs as due to a small decrease of rotational constants upon excitation of excited electronic states. Along with radiative pumping of a great many high-J rotational levels, this causes the ETRs. In order to study this effect quantitatively, we have developed a model calculation in which the effects of collision and radiation are treated simultaneously. The simplest case of linear molecules is considered. It has been found that the ETR is reproduced if the fraction of the variation of the rotational constant, beta = (B-B)/B, is sufficiently high (3-5%) and the radiative temperature is high (T_r > 50 K). Although modeling for general molecules is beyond the scope of this paper, the results indicate that the prototypical DIBs at 5780.5, 5797.1, and 6613.6 A which show the pronounced ETRs are due to polar molecules sensitive to the radiative excitation. The requirement of high beta favors relatively small molecules with 3-6 heavy atoms. DIBs at 5849.8, 6196.0, and 6379.3 A which do not show the pronounced ETRs are likely due to non-polar molecules or large polar molecules with small beta.

Probing the Local Bubble with Diffuse Interstellar Bands (DIBs)

The Sun lies in the middle of an enormous cavity of a million degree gas, known as the Local Bubble. The Local Bubble is surrounded by a wall of denser neutral and ionized gas. The Local Bubble extends around 100 pc in the plane of Galaxy and hundreds of parsecs vertically, but absorption-line surveys of neutral sodium and singly-ionized calcium have revealed a highly irregular structure and the presence of neutral clouds within an otherwise tenuous and hot gas. We have undertaken an all-sky, European-Iranian survey of the Local Bubble in the absorption of a number of diffuse interstellar bands (DIBs) to offer a novel view of our neighbourhood. Our dedicated campaigns with ESOs New Technology Telescope and the INGs Isaac Newton Telescope comprise high signal-to-noise, medium-resolution spectra, concentrating on the 5780 and 5797 AA bands which trace ionized/irradiated and neutral/shielded environments, respectively; their carriers are unknown but likely to be large carbonaceous molecules. With about 660 sightlines towards early-type stars distributed over distances up to about 200 pc, our data allow us to reconstruct the first ever 3D DIB map of the Local Bubble, which we present here. While we confirm our expectations that the 5780 AA DIB is relatively strong compared to the 5797 AA DIB in hot/irradiated regions such as which prevail within the Local Bubble and its walls, and the opposite is true for cooler/shielded regions beyond the confines of the Local Bubble, we unexpectedly also detect DIB cloudlets inside of the Local Bubble. These results reveal new insight into the structure of the Local Bubble, as well as helping constrain our understanding of the carriers of the DIBs.

Spatial distribution of FIR rotationally excited CH+ and OH emission lines in the Orion Bar PDR

The abundance of CH+ and OH and excitation are predicted to be enhanced by the presence of vibrationally excited H2 or hot gas (~500-1000 K) in PDRs with high incident FUV radiation field. The excitation may also originate in dense gas (>10^5 cm-3) followed by nonreactive collisions. Previous observations suggest that the CH+ and OH correlate with dense and warm gas, and formation pumping contributes to CH+ excitation. We examine the spatial distribution of the CH+ and OH emission in the Orion Bar to establish their physical origin and main formation and excitation mechanisms. We present spatially sampled maps of the CH+ J=3-2 transition at 119.8 {mu}m and the OH {Lambda}-doublet at 84 {mu}m in the Orion Bar over an area of 110x110 with Herschel (PACS). We compare the spatial distribution of these molecules with those of their chemical precursors, C+, O and H2, and tracers of warm and dense gas. We assess the spatial variation of CH+ J=2-1 velocity-resolved line profile observed with Herschel (HIFI). The OH and CH+ lines correlate well with the high-J CO emission and delineate the warm and dense molecular region. While similar, the differences in the CH+ and OH morphologies indicate that CH+ formation and excitation are related to the observed vibrationally excited H2. This indicates that formation pumping contributes to the excitation of CH+. Interestingly, the peak of the rotationally excited OH 84 {mu}m emission coincides with a bright young object, proplyd 244-440, which shows that OH can be an excellent tracer of UV-irradiated dense gas. The spatial distribution of CH+ and OH revealed in our maps is consistent with previous modeling studies. Both formation pumping and nonreactive collisions in a UV-irradiated dense gas are important CH+ J=3-2 excitation processes. The excitation of the OH {Lambda}-doublet at 84 {mu}m is mainly sensitive to the temperature and density.

Near-Infrared Diffuse Interstellar Bands towards Her 36

Discovered almost a century ago, the Diffuse Interstellar Bands (DIBs) still lack convincing and comprehensive identification. Hundreds of DIBs have now been observed in the near-ultraviolet (NUV), visible and near-infrared (NIR). They are widely held to be molecular in origin, and modelling of their band profiles offers powerful constraints on molecular constants. Herschel 36, the illuminating star of the Lagoon Nebula, has been shown to possess unusually broad and asymmetric DIB profiles in the visible, and is also bright enough for NIR observation. We present here high-resolution spectroscopic observations targeting the two best-known NIR DIBs at 11797.5 and 13175 A toward this object and a nearby comparison O-star, 9 Sgr, using the GNIRS instrument on Gemini North. We show a clear detection of the 13175 A DIB in both stars, and find (i) that it does not exhibit the unusual wing structure of some of the visual DIBs in Her 36 and (ii) that the depth of the band in the two objects is very similar, also contrary to the behaviour of the visual DIBs. We discuss the implications of these results for multiple DIB carrier candidates, and the location of their carriers along the observed lines of sight.

Strong CH+ J=1-0 emission and absorption in DR21

We report the first detection of the ground-state rotational transition of the methylidyne cation CH+ towards the massive star-forming region DR21 with the HIFI instrument onboard the Herschel satellite. The line profile exhibits a broad emission line, in addition to two deep and broad absorption features associated with the DR21 molecular ridge and foreground gas. These observations allow us to determine a CH+ J=1-0 line frequency of 835137 +/- 3 MHz, in good agreement with a recent experimental determination. We estimate the CH+ column density to be a few 1e13 cm^-2 in the gas seen in emission, and > 1e14 cm^-2 in the components responsible for the absorption, which is indicative of a high line of sight average abundance [CH+]/[H] > 1.2x10^-8. We show that the CH+ column densities agree well with the predictions of state-of-the-art C-shock models in dense UV-illuminated gas for the emission line, and with those of turbulent dissipation models in diffuse gas for the absorption lines.