اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدCreate Dirac Cones in Your Favorite Materials
110
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
Realization of conically linear dispersion, termed as Dirac cones, has recently opened up exciting opportunities for high-performance devices that make use of the peculiar transport properties of the massless carriers. A good example of current fashion is the heavily studied graphene, a single atomic layered graphite. It not only offers a prototype of Dirac physics in the field of condensed matter and materials science, but also provides a playground of various exotic phenomena. In the meantime, numerous routes have been attempted to search for the next graphene. Despite these efforts, to date there is still no simple guideline to predict and engineer such massless particles in materials. Here, we propose a theoretical recipe to create Dirac cones into anyones favorite materials. The method allows to tailor the properties, such as anisotropy and quantity, in any effective one-band two-dimensional lattice. We demonstrate the validity of our theory with two examples on the square lattice, an unlikely candidate hosting Dirac cones, and show that a graphene-like low-energy electronic structure can be realized. The proposed recipe can be applied in real materials via introduction of vacancy, substitution or intercalation, and also extended to photonic crystal, molecular array, and cold atoms systems.
قيم البحث
اقرأ أيضاً
A wide range of materials, like d-wave superconductors, graphene, and topological insulators, share a fundamental similarity: their low-energy fermionic excitations behave as massless Dirac particles rather than fermions obeying the usual Schrodinger
Hamiltonian. This emergent behavior of Dirac fermions in condensed matter systems defines the unifying framework for a class of materials we call Dirac materials. In order to establish this class of materials, we illustrate how Dirac fermions emerge in multiple entirely different condensed matter systems and we discuss how Dirac fermions have been identified experimentally using electron spectroscopy techniques (angle-resolved photoemission spectroscopy and scanning tunneling spectroscopy). As a consequence of their common low-energy excitations, this diverse set of materials shares a significant number of universal properties in the low-energy (infrared) limit. We review these common properties including nodal points in the excitation spectrum, density of states, specific heat, transport, thermodynamic properties, impurity resonances, and magnetic field responses, as well as discuss many-body interaction effects. We further review how the emergence of Dirac excitations is controlled by specific symmetries of the material, such as time-reversal, gauge, and spin-orbit symmetries, and how by breaking these symmetries a finite Dirac mass is generated. We give examples of how the interaction of Dirac fermions with their distinct real material background leads to rich novel physics with common fingerprints such as the suppression of back scattering and impurity-induced resonant states.
Atomic scale engineering of two-dimensional materials could create devices with rich physical and chemical properties. External periodic potentials can enable the manipulation of the electronic band structures of materials. A prototypical system is 3
x3-silicene/Ag(111), which has substrate-induced periodic modulations. Recent angle-resolved photoemission spectroscopy measurements revealed six Dirac cone pairs at the Brillouin zone boundary of Ag(111), but their origin remains unclear [Proc. Natl. Acad. Sci. USA 113, 14656 (2016)]. We used linear dichroism angle-resolved photoemission spectroscopy, the tight-binding model, and first-principles calculations to reveal that these Dirac cones mainly derive from the original cones at the K (K) points of free-standing silicene. The Dirac cones of free-standing silicene are split by external periodic potentials that originate from the substrate-overlayer interaction. Our results not only confirm the origin of the Dirac cones in the 3x3-silicene/Ag(111) system, but also provide a powerful route to manipulate the electronic structures of two-dimensional materials.
By band engineering the iron chalcogenide Fe(Se,Te) via ab-initio calculations, we search for topological surface states and realizations of Majorana bound states. Proposed topological states are expected to occur for non-stoichiometric compositions
on a surface Dirac cone where issues like disorder scattering and charge transfer between relevant electronic states have to be addressed. However, this surface Dirac cone is well above the Fermi-level. Our goal is to theoretically design a substituted crystal in which the surface Dirac cone is shifted towards the Fermi-level by modifying the bulk material without disturbing the surface. Going beyond conventional density functional theory (DFT), we apply the coherent potential approximation (BEB-CPA) in a mixed basis pseudo-potential framework to scan the substitutional phase-space of co-substitutions on the Se-sites. We have identified iodine as a promising candidate for intrinsic doping. Our specific proposal is that FeSe$_{0.325}$I$_{0.175}$Te$_{0.5}$ is a very likely candidate to exhibit a Dirac cone right at the Fermi energy without inducing strong disorder scattering.
Theoretical evidence of the existence of 12 inequivalent Dirac cones at the vicinity of the Fermi energy in monolayered ZrB$_2$ is presented. Two-dimensional ZrB$_2$ is a mechanically stable d- and p-orbital compound exhibiting a unique electronic st
ructure with two Dirac cones out of high-symmetry points in the irreducible Brillouin zone with a small electron-pocket compensation. First-principles calculations demonstrate that while one of the cones is insensitive to lattice expansion, the second cone vanishes for small perturbation of the vertical Zr position. Internal symmetry breaking with external physical stimuli, along with the relativistic effect of SOC, is able to remove selectively the Dirac cones. A rational explanation in terms of d- and p-orbital mixing is provided to elucidate the origin of the infrequent amount of Dirac cones in a flat structure. The versatility of transition metal d-orbitals combined with the honeycomb lattice provided by the B atoms yields novel features never observed in a two-dimensional material.
Artificial lattices provide a tunable platform to realize exotic quantum devices. A well-known example is artificial graphene (AG), in which electrons are confined in honeycomb lattices and behave as massless Dirac fermions. Recently, AG systems have
been constructed by manipulating molecules using scanning tunnelling microscope tips, but the nanoscale size typical for these constructed systems are impossible for practical device applications and insufficient for direct investigation of the electronic structures using angle-resolved photoemission spectroscopy (ARPES). Here, we demonstrate the synthesis of macroscopic AG by self-assembly of C$_{60}$ molecules on metal surfaces. Our theoretical calculations and ARPES measurements directly confirm the existence of Dirac cones at the $K$ ($K^prime$) points of the Brillouin zone (BZ), in analogy to natural graphene. These results will stimulate ongoing efforts to explore the exotic properties in artificial lattices and provide an important step forward in the realization of novel molecular quantum devices.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
