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We report on the observation of magnetic dipole allowed transitions in the well-characterized $A,^2Sigma^+ - X,^2Pi$ band system of the OH radical. A Stark decelerator in combination with microwave Rabi spectroscopy is used to control the populations in selected hyperfine levels of both $Lambda$-doublet components of the $X,^2Pi_{3/2},v=0,J=3/2$ ground state. Theoretical calculations presented in this paper predict that the magnetic dipole transitions in the $ u=1 leftarrow u=0$ band are weaker than the electric dipole transitions by a factor of $2.58times 10^3$ only, i.e., much less than commonly believed. Our experimental data confirm this prediction.
Rotationally resolved spectra of the C$^2Sigma^+$-X$^2Pi$ electronic system of the CH radical were measured using cavity ring-down spectroscopy in supersonically expanding, planar hydrocarbon plasma. The experimental conditions allowed the study of h
We use accurate quantum mechanical calculations to analyze the effects of parallel electric and magnetic fields on collision dynamics of OH(2Pi) molecules. It is demonstrated that spin relaxation in 3He-OH collisions at temperatures below 0.01 K can
We present detailed calculations on resonances in rotationally and spin-orbit inelastic scattering of OH ($X,^2Pi, j=3/2, F_1, f$) radicals with He and Ne atoms. We calculate new emph{ab initio} potential energy surfaces for OH-He, and the cross sect
We have reflected a Stark-decelerated beam of OH molecules under normal incidence from mirrors consisting of permanent magnets. Two different types of magnetic mirrors have been demonstrated. A long-range flat mirror made from a large disc magnet has
Resonant inelastic x-ray scattering (RIXS) provides remarkable opportunities to interrogate ultrafast dynamics in liquids. Here we use RIXS to study the fundamentally and practically important hydroxyl radical in liquid water, OH(aq). Impulsive ioniz