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We report the first observation of photoassociation to the 2(1)Sigma(g)(+) state of 85Rb2 . We have observed two vibrational levels (v=98, 99) below the 5s1/2+5p1/2 atomic limit and eleven vibrational levels (v=102-112) above it. The photoassociation---and subsequent spontaneous emission---occur predominantly between 15 and 20 Bohr in a region of internuclear distance best described as a transition between Hunds case (a) and Hunds case (c) coupling. The presence of a g-wave shape resonance in the collision of two ground-state atoms affects the photoassociation rate and lineshape of the J= 3 and 5 rotational levels.
We report on the anomalously high line strength of a single rotational level in the ultracold photoassociation of two 85Rb atoms to form 85Rb2. The v = 111, J = 5 level belongs to the Hunds case (c) 2 (0g+) state, which correlates to the Hunds case (
We report on measurements of the binding energies of several weakly bound vibrational states of the paramagnetic $^{174}$Yb$^{6}$Li molecule in the electronic ground state using two-photon spectroscopy in an ultracold atomic mixture confined in an op
We present experimental observations of seven vibrational levels $v=20-26$ of the $1^{3}Sigma_{g}^{+}$ excited state of Li$_2$ molecules by the photoassociation (PA) of a degenerate Fermi gas of $^6$Li atoms. For each vibrational level, we resolve th
We study the time-resolved photoassociation of ultracold sodium in an optical dipole trap. The photoassociation laser excites pairs of atoms to molecular states of large total angular momentum at high intensities (above 20 kW/cm$^{2}$). Such transiti
We perform photoassociation spectroscopy in an ultracold $^{23}$Na-$^6$Li mixture to study the $c^3Sigma^+$ excited triplet molecular potential. We observe 50 vibrational states and their substructure to an accuracy of 20 MHz, and provide line streng