Quasiparticle dynamics of FeSe single crystals revealed by dual-color transient reflectivity measurements ({Delta}R/R) provides unprecedented information on Fe-based superconductors. The amplitude of fast component in {Delta}R/R clearly tells a competing scenario between spin fluctuations and superconductivity. Together with the transport measurements, the relaxation time analysis further exhibits anomalous changes at 90 K and 230 K. The former manifests a structure phase transition as well as the associated phonon softening. The latter suggests a previously overlooked phase transition or crossover in FeSe. The electron-phonon coupling constant {lambda} is found to be 0.16, identical to the value of theoretical calculations. Such a small {lambda} demonstrates an unconventional origin of superconductivity in FeSe.
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