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Magnetic ferroelectric has been found in a wide range of spiral magnets. However, these materials all suffer from low critical temperatures, which are usually below 40 K, due to strong spin frustration. Recently, CuO has been found to be multiferroic at much higher ordering temperature ($sim$ 230K). To clarify the origin of the high ordering temperature in CuO, we investigate the structural, electronic and magnetic properties of CuO via first-principles methods. We find that CuO has very special nearly commensurate spiral magnetic structure, which is stabilized via the Dzyaloshinskii-Moriya interaction. The spin frustration in CuO is relatively weak, which is one of the main reasons that the compound have high ordering temperature. We propose that high $T_c$ magnetic ferroelectric materials can be found in double sublattices of magnetic structures similar to that of CuO.
Cupric oxide is a unique magnetic ferroelectric material with a transition temperature significantly higher than the boiling point of liquid nitrogen. However, the mechanism of high-T$_c$ multiferroicity in CuO remains puzzling. In this paper, we cla
The successful theoretical prediction and experimental demonstration of hybrid improper ferroelectricity (HIF) provides a new pathway to couple octahedral rotations, ferroelectricity, and magnetism in complex materials. To enable technological applic
Ferroelectric hafnia is being explored for next generation electronics due to its robust ferroelectricity in nanoscale samples and its compatibility with silicon. However, its ferroelectricity is not understood. Other ferroelectrics usually lose thei
Remarkably high values of polarization as well as a significant magnetic susceptibility have been observed in multiferroic Bismuth Ferrite (BFO) in the form of nanorods protruding out. These were developed on porous Anodised Alumina (AAO) templates u
High resolution ultrasonic velocity measurements have been used to determine the temperature -- magnetic-field phase diagram of the monoclinic multiferroic CuO. A new transition at TN3 = 230 K, corresponding to an intermediate state between the antif