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We have observed the J=3-2 transition of N2H+ and N2D+ to investigate the trend of deuterium fractionation with evolutionary stage in three selected regions in the Infrared Dark Cloud (IRDC) G28.34+0.06 with the Submillimeter Telescope (SMT) and the Submillimeter Array (SMA). A comprehensible enhancement of roughly 3 orders of magnitude in deuterium fractionation over the local interstellar D/H ratio is observed in all sources. In particular, our sample of massive star-forming cores in G28.34+0.06 shows a moderate decreasing trend over a factor of 3 in the N(N2D+)/N(N2H+) ratio with evolutionary stage, a behavior resembling what previously found in low-mass protostellar cores. This suggests a possible extension for the use of the N(N2D+)/N(N2H+) ratio as an evolutionary tracer to high-mass protostellar candidates. In the most evolved core, MM1, the N2H+ (3-2) emission appears to avoid the warm region traced by dust continuum emission and emission of 13CO sublimated from grain mantles, indicating an instant release of gas-phase CO. The majority of the N2H+ and N2D+ emission is associated with extended structures larger than 8 (~ 0.2 pc).
Clouds of high infrared extinction are promising sites of massive star/cluster formation. A large number of cloud cores discovered in recent years allows investigation of possible evolutionary sequence among cores in early phases. We have conducted a
Nitrogen is one of the most abundant elements in the Universe and its 14N/15N isotopic ratio has the potential to provide information about the initial environment in which our Sun formed. Recent findings suggest that the Solar System may have formed
We have performed a pointed survey of N2D+ 2-1 and N2D+ 3-2 emission toward 64 N2H+-bright starless and protostellar cores in the Perseus molecular cloud using the Arizona Radio Observatory Submillimeter Telescope and Kitt Peak 12 m telescope. We fin
The deuterium fraction [N$_2$D$^+$]/[N$_2$H$^+$], may provide information about the ages of dense, cold gas structures, important to compare with dynamical models of cloud core formation and evolution. Here we introduce a complete chemical network wi
Infrared Dark Clouds (IRDCs) are very dense and highly extincted regions that host the initial conditions of star and stellar cluster formation. It is crucial to study the kinematics and molecular content of IRDCs to test their formation mechanism an