Enhanced polarization conversion in reflection for the Otto and Kretschmann configurations is introduced as a new method for hybrid-mode spectroscopy. Polarization conversion in reflection appears when hybrid-modes are excited in a guiding structure composed of at least one anisotropic media. In contrast to a dark dip, in this case modes are associated to a peak in the converted reflectance spectrum, increasing the detection sensitivity and avoiding confusion with reflection dips associated with other processes as can be transmission.