ترغب بنشر مسار تعليمي؟ اضغط هنا

Dynamics of a colloidal glass during stress-mediated structural arrest

459   0   0.0 ( 0 )
 نشر من قبل Chinedum Osuji
 تاريخ النشر 2009
  مجال البحث فيزياء
والبحث باللغة English




اسأل ChatGPT حول البحث

We employ parallel superposition rheology to study the dynamics of an aging colloidal glass in the presence of a mean field stress. Over a range of intermediate stresses, the loss modulus exceeds the storage modulus at short times but develops a maximum concomitant with a crossover between the two as the system ages. This is attended by a narrowing of the loss peak on increasing stress. We show that this feature is characteristic of the structural arrest in these materials, which is made observable on reasonable timescales by the activating influence of the stress. The arrest time displays an exponential dependence on inverse stress. These results provide experimental validation of the role of stress as an effective temperature in soft glassy systems as has been advanced in recent theoretical frameworks.



قيم البحث

اقرأ أيضاً

Evolution of the energy landscape during physical aging of glassy materials can be understood from the frequency and strain dependence of the shear modulus but the non-stationary nature of these systems frustrates investigation of their instantaneous underlying properties. Using a series of time dependent measurements we systematically reconstruct the frequency and strain dependence as a function of age for a repulsive colloidal glass undergoing structural arrest. In this manner, we are able to unambiguously observe the structural relaxation time, which increases exponentially with sample age at short times. The yield stress varies logarithmically with time in the arrested state, consistent with recent simulation results, whereas the yield strain is nearly constant in this regime. Strikingly, the frequency dependence at fixed times can be rescaled onto a master curve, implying a simple connection between the aging of the system and the change in the frequency dependent modulus.
In this work, we study ageing behavior of aqueous laponite suspension, a model soft glassy material, in creep. We observe that viscoelastic behavior is time dependent and is strongly influenced by the deformation field; the effect is known to arise d ue to ageing and rejuvenation. We show that irrespective of strength of deformation field (shear stress) and age, when imposed time-scale is normalized with dominating relaxation mode of the system, universal ageing behavior is obtained demonstrating time-stress superposition; the phenomena that may be generic in variety of soft materials.
68 - F. Ozon , T. Narita , A. Knaebel 2002
We study the effect of shear on the aging dynamics of a colloidal suspension of synthetic clay particles. We find that a shear of amplitude $gamma$ reduces the relaxation time measured just after the cessation of shear by a factor $exp(-gamma/gamma_c )$, with $gamma_c sim 5%$, and is independent of the duration and the frequency of the shear. This simple law for the rejuvenation effect shows that the energy involved in colloidal rearrangements is proportional to the shear amplitude, $gamma$, rather than $gamma^2$, leading to an Eyring-like description of the dynamics of our system.
We study experimentally the origin of heterogeneous dynamics in strongly driven glass-forming systems. Thereto, we apply a well-defined force with a laser line trap on individual colloidal polystyrene probe particles seeded in an emulsion glass compo sed of droplets of the same size. Fluid and glass states can be probed. We monitor the trajectories of the probe and measure displacements and their distributions. Our experiments reveal intermittent dynamics around a depinning transition at a threshold force. For smaller forces, linear response connects mean displacement and quiescent mean squared displacement. Mode coupling theory calculations rationalize the observations.
One of the central problems of the liquid-glass transition is whether there is a structural signature that can qualitatively distinguish different dynamic behaviors at different degrees of supercooling. Here, we propose a novel structural characteriz ation based on the spatial correlation of local density and we show the locally dense-packed structural environment has a direct link with the slow dynamics as well as dynamic heterogeneity in glass-formers. We find that particles with large local density relax slowly and the size of cluster formed by the dense-packed particles increases with decreasing the temperature. Moreover, the extracted static length scale shows clear correlation with the relaxation time at different degrees of supercooling. This suggests that the temporarily but continuously formed locally dense-packed structural environment may be the structural origin of slow dynamics and dynamic heterogeneity of the glass-forming liquids.
التعليقات
جاري جلب التعليقات جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
mircosoft-partner

هل ترغب بارسال اشعارات عن اخر التحديثات في شمرا-اكاديميا