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A class of local SU(2)-invariant spin-1/2 Hamiltonians is studied that has ground states within the space of nearest neighbor valence bond states on the kagome lattice. Cases include generalized Klein models without obvious non-valence bond ground states, as well as a resonating-valence-bond Hamiltonian whose unique ground states within the nearest neighbor valence bond space are four topologically degenerate Sutherland-Rokhsar-Kivelson (SRK) type wavefunctions, which are expected to describe a gapped $mathbb{Z}_2$ spin liquid. The proof of this uniqueness is intimately related to the linear independence of the nearest neighbor valence bond states on quite general and arbitrarily large kagome lattices, which is also established in this work. It is argued that the SRK ground states are also unique within the entire Hilbert space, depending on properties of the generalized Klein models. Applications of the strategies developed in this work to other lattice types are also discussed.
The spin-$frac{1}{2}$ kagome antiferromagnet is considered an ideal host for a quantum spin liquid ground state. We find that when the bonds of the kagome lattice are modulated with a periodic pattern, new quantum ground states emerge. Newly synthesi
The vanadium oxyfluoride [NH4]2[C7H14N][V7O6F18] (DQVOF) is a geometrically frustrated magnetic bilayer material. The structure consists of S=1/2 kagome planes of V4+ d1 ions with S=1 V3+ d2 ions located between the kagome layers. Muon spin relaxatio
The properties of ground state of spin-$frac{1}{2}$ kagome antiferromagnetic Heisenberg (KAFH) model have attracted considerable interest in the past few decades, and recent numerical simulations reported a spin liquid phase. The nature of the spin l
The honeycomb lattice material Li2RuO3 undergoes a dimerization of Ru4+ cations on cooling below 270C, where the magnetic susceptibility vanishes. We use density functional theory calculations to show that this reflects the formation of a valence bon
We revisit the description of the low-energy singlet sector of the spin-1/2 Heisenberg antiferromagnet on kagome in terms of an effective quantum dimer model. With the help of exact diagonalizations of appropriate finite-size clusters, we show that t