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We have investigated the role of molecular anion chemistry in pseudo-time dependent chemical models of dark clouds. With oxygen-rich elemental abundances, the addition of anions results in a slight improvement in the overall agreement between model results and observations of molecular abundances in TMC-1 (CP). More importantly, with the inclusion of anions, we see an enhanced production efficiency of unsaturated carbon-chain neutral molecules, especially in the longer members of the families CnH, CnH2, and HCnN. The use of carbon-rich elemental abundances in models of TMC-1 (CP) with anion chemistry worsens the agreement with observations obtained in the absence of anions.
We have analysed the chemical and kinematic properties of the 20 and 50 km s$^{-1}$ molecular clouds in the Central Molecular Zone of the Milky Way Galaxy, as well as those of the molecular ridge bridging these two clouds. Our work has utilized 37 mo
We show that the inter-cloud Larson scaling relation between mean volume density and size $rhopropto R^{-1}$, which in turn implies that mass $Mpropto R^2$, or that the column density $N$ is constant, is an artifact of the observational methods used.
We study Giant Molecular Cloud (GMC) environments surrounding 10 Infrared Dark Clouds (IRDCs), using $^{13}$CO(1-0) emission from the Galactic Ring Survey. We measure physical properties of these IRDCs/GMCs on a range of scales extending to radii, R,
We present a general parameter study, in which the abundance of interstellar argonium (ArH$^+$) is predicted using a model for the physics and chemistry of diffuse interstellar gas clouds. Results have been obtained as a function of UV radiation fiel
The 1-50 GHz GBT PRIMOS data contains ~50 molecular absorption lines observed in diffuse and translucent clouds located in the Galactic Center, Bar, and spiral arms in the line-of-sight to Sgr B2(N). We measure the column densities and estimate abund