اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدPhonon density of states, anharmonicity, electron-phonon coupling and possible multigap superconductivity in the clathrate superconductors Ba8Si46 and Ba24Si100: Why is Tc different in these two compounds?
223
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
We report a detailed study of specific heat, electrical resistivity and thermal expansion in combination with inelastic neutron and inelastic X-ray scattering to investigate the origin of superconductivity in the two silicon clathrate superconductors Ba8Si46 and Ba24Si100. Both compounds have a similar structure based on encaged barium atoms in oversized silicon cages. However, the transition temperatures are rather different: 8 K and 1.5 K respectively. By extracting the superconducting properties, phonon density of states, electron-phonon coupling function and phonon anharmonicity from these measurements we discuss the important factors governing Tc and explain the difference between the two compounds.
قيم البحث
اقرأ أيضاً
Density-functional calculations of the phonon spectrum and electron-phonon coupling in MgB$_2$ are presented. The $E_{2g}$ phonons, which involve in-plane B displacements, couple strongly to the $p_{x,y}$ electronic bands. The isotropic electron-phon
on coupling constant is calculated to be about 0.8. Allowing for different order parameters in different bands, the superconducting $lambda$ in the clean limit is calculated to be significantly larger. The $E_{2g}$ phonons are strongly anharmonic, and the non-linear contribution to the coupling between the $E_{2g}$ modes and the p$_{x,y}$ bands is significant.
The strong coupling Eliashberg theory plus vertex correction is used to calculate maps of transition temperature (Tc) in parameter-space characterizing superconductivity. Based on these Tc maps, crossover behaviors are found when electron-phonon inte
raction increases from weak-coupling region to strong coupling region. Especially, the combined interaction of vertex correction and Coulomb interaction can efficiently depress Tc from extremely high values in standard strong-coupling theory to reasonable values found in experiments and successfully explain the doing-dependent Tc of cuprate superconductors. The strong non-adiabatic effect is the barrier for high-Tc in compounds with compositions of light atoms and with high phonon frequencies.
We have studied the quasiparticle excitation spectrum of the superconductor Ba8Si46 by local tunneling spectroscopy. Using high energy resolution achieved in Superconductor-Superconductor junctions we observed tunneling conductance spectra of a non-c
onventional shape revealing two distinct energy gaps, DeltaL = 1.3meV and DeltaS = 0.9meV. The analysis of tunneling data evidenced that DeltaL is the principal superconducting gap while DeltaS, smaller and more dispersive, is induced into an intrinsically non-superconducting band of the material by the inter-band quasiparticle scattering.
Phonon measurements in the A15-type superconductors were complicated in the past because of the unavailability of large single crystals for inelastic neutron scattering, e.g., in the case of Nb$_3$Sn, or unfavorable neutron scattering properties in t
he case of V$_3$Si. Hence, only few studies of the lattice dynamical properties with momentum resolved methods were published, in particular below the superconducting transition temperature $T_c$. Here, we overcome these problems by employing inelastic x-ray scattering and report a combined experimental and theoretical investigation of lattice dynamics in V$_3$Si with the focus on the temperature-dependent properties of low-energy acoustic phonon modes in several high-symmetry directions. We paid particular attention to the evolution of the soft phonon mode of the structural phase transition observed in our sample at $T_s=18.9,rm{K}$, i.e., just above the measured superconducting phase transition at $T_c=16.8,rm{K}$. Theoretically, we predict lattice dynamics including electron-phonon coupling based on density-functional-perturbation theory and discuss the relevance of the soft phonon mode with regard to the value of $T_c$. Furthermore, we explain superconductivityinduced anomalies in the lineshape of several acoustic phonon modes using a model proposed by Allen et al., [Phys. Rev. B 56, 5552 (1997)].
Phonon density of states (PDOS) measurements have been performed on polycrystalline UO2 at 295 and 1200 K using time-of-flight inelastic neutron scattering to investigate the impact of anharmonicity on the vibrational spectra and to benchmark ab init
io PDOS simulations performed on this strongly correlated Mott-insulator. Time-of-flight PDOS measurements include anharmonic linewidth broadening inherently and the factor of ~ 7 enhancement of the oxygen spectrum relative to the uranium component by the neutron weighting increases sensitivity to the oxygen-dominated optical phonon modes. The first-principles simulations of quasi-harmonic PDOS spectra were neutron-weighted and anharmonicity was introduced in an approximate way by convolution with wavevector-weighted averages over our previously measured phonon linewidths for UO2 that are provided in numerical form. Comparisons between the PDOS measurements and the simulations show reasonable agreement overall, but they also reveal important areas of disagreement for both high and low temperatures. The discrepancies stem largely from an ~ 10 meV compression in the overall bandwidth (energy range) of the oxygen-dominated optical phonons in the simulations. A similar linewidth-convoluted comparison performed with the PDOS spectrum of Dolling et al. obtained by shell-model fitting to their historical phonon dispersion measurements shows excellent agreement with the time-of-flight PDOS measurements reported here. In contrast, we show by comparisons of spectra in linewidth-convoluted form that recent first-principles simulations for UO2 fail to account for the PDOS spectrum determined from the measurements of Dolling et al. These results demonstrate PDOS measurements to be stringent tests for ab initio simulations of phonon physics in UO2 and they indicate further the need for advances in theory to address lattice dynamics of UO2.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
