اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدHollow carbon spheres as an efficient dopant for enhancing critical current density of MgB2 based tapes
452
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
A significant enhancement of Jc and Hirr in MgB2 tapes has been achieved by the in situ powder-in-tube method utilizing hollow carbon spheres (HCS) as dopants. At 4.2 K, the transport Jc for the 850C sintered samples reached 3.1x10^4, and 1.4x10^4 A/cm^2 at 10 and 12 T, respectively, and were better than those of optimal nano-SiC doped tapes. Furthermore, the Hirr for doped sample was raised up to 16.8 T at 10 K due to the carbon substitution effect. The results demonstrate that HCS is one of the most promising dopants besides nano-carbon and SiC for the enhancement of current capacity for MgB2 in high fields.
قيم البحث
اقرأ أيضاً
Ex-situ Powder-In-Tube MgB2 tapes prepared with ball-milled, undoped powders showed a strong enhancement of the irreversibility field H*, the upper critical field Hc2 and the critical current density Jc(H) together with the suppression of the anisotr
opy of all of these quantities. Jc reached 104 A/cm2 at 4.2 K and 10 T, with an irreversibility field of about 14 T at 4.2 K, and Hc2 of 9 T at 25 K, high values for not-doped MgB2. The enhanced Jc and H* values are associated with significant grain refinement produced by milling of the MgB2 powder, which enhances grain boundary pinning, although at the same time also reducing the connectivity from about 12% to 8%. Although enhanced pinning and diminished connectivity are in opposition, the overall influence of ball milling on Jc is positive because the increased density of grains with a size comparable with the mean free path produces strong electron scattering that substantially increases Hc2, especially Hc2 perpendicular to the Mg and B planes.
The effect of the quality of starting powders on the microstructure and superconducting properties of in-situ processed Fe-sheathed MgB2 tapes has been investigated. Three different types of commercial atomized spherical magnesium powder and two diff
erent purities of amorphous boron powder were employed. When using the 10-micrometre magnesium as precursor powders, the Mg reacted with boron more uniformly and quickly, thus the uniformity of the fabricated MgB2 was improved and the grain size of the MgB2 was decreased, hence significant critical current density (Jc) enhancements were achieved for MgB2 tapes. Jc at 4.2 K for MgB2 tapes made from the 10 um Mg and high purity boron powders was at least a factor of ten higher than values measured for MgB2 samples made from all other starting powders. At 20 K, 5 T, the typical Jc values of the tapes were over 1.0x10^4 A/cm^2 and were much better than those of tape samples reported recently.
MgB2/Fe tapes with 2.5-15 at.% ZrB2 additions were prepared through the in situ powder-in-tube method. Compared to the pure tape, a significant improvement in the in-field critical current density Jc was observed, most notably for 10 at.% doping, whi
le the critical temperature decreased slightly. At 4.2 K, the transport Jc for the 10 at.% doped sample increased by more than an order of magnitude than the undoped one in magnetic fields above 9 T. Nanoscale segregates or defects caused by the ZrB2 additions which act as effective flux pinning centers are proposed to be the main reason for the improved Jc field performance.
The high resistivity of many bulk and film samples of MgB2 is most readily explained by the suggestion that only a fraction of the cross-sectional area of the samples is effectively carrying current. Hence the supercurrent (Jc) in such samples will b
e limited by the same area factor, arising for example from porosity or from insulating oxides present at the grain boundaries. We suggest that a correlation should exist, Jc ~ 1/{Rho(300K) - Rho(50K)}, where Rho(300K) - Rho(50K) is the change in the apparent resistivity from 300 K to 50 K. We report measurements of Rho(T) and Jc for a number of films made by hybrid physical-chemical vapor deposition which demonstrate this correlation, although the reduced effective area argument alone is not sufficient. We suggest that this argument can also apply to many polycrystalline bulk and wire samples of MgB2.
The DC magnetization and AC complex magnetic susceptibilities were measured for MgB2 single crystals, unsubstituted and carbon substituted with the composition of Mg(B_0.94C_0.06)2. The measurements were performed in AC and DC magnetic fields oriente
d parallel to the c-axis of the crystals. From the DC magnetization loops and the AC susceptibility measurements, critical current densities (Jc) were derived as a function of temperature and the DC and AC magnetic fields. Results show that the substitution with carbon decreases Jc at low magnetic fields, opposite to the well known effect of an increase of Jc at higher fields. AC magnetic losses were derived from the AC susceptibility data as a function of amplitude and the DC bias magnetic field. The AC losses were determined for temperatures of 0.6 and 0.7 of the transition temperature Tc, so close to the boiling points of LH2 and LNe, potential cooling media for magnesium diboride based composites. The results are analyzed and discussed in the context of the critical state model.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
