We report on the discovery of J0644+3344, a bright deeply eclipsing cataclysmic variable (CV) binary. Spectral signatures of both binary components and an accretion disk can be seen at optical wavelengths. The optical spectrum shows broad H I, He I, and He II accretion disk emission lines with deep narrow absorption components from H I, He I, Mg II and Ca II. The absorption lines are seen throughout the orbital period, disappearing only during primary eclipse. These absorption lines are either the the result of an optically-thick inner accretion disk or from the photosphere of the primary star. Radial velocity measurements show that the H I, He I, and Mg II absorption lines phase with the the primary star, while weak absorption features in the continuum phase with the secondary star. Radial velocity solutions give a 150+/-4 km/s semi-amplitude for the primary star and 192.8+/-5.6 km/s for the secondary. The individual stellar masses are 0.63-0.69 Mdot for the primary and 0.49-0.54 Mdot for the secondary. The bright eclipsing nature of this binary has helped provide masses for both components with an accuracy rarely achieved for CVs. This binary most closely resembles a nova-like UX UMa or SW Sex type of CV. J0644+3344, however, has a longer orbital period than most UX UMa or SW Sex stars. Assuming an evolution toward shorter orbital periods, J0644+3344 is therefore likely to be a young interacting binary. The secondary star is consistent with the size and spectral type of a K8 star, but has an M0 mass.
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