اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدDirect observation of mixing of spin-multiplets in an antiferromagnetic molecular nanomagnet by electron paramagnetic resonance
239
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
High-frequency electron paramagnetic resonance (EPR) studies of the antiferromagnetic Mn-$[3times 3]$ molecular grid clearly reveal a breaking of the $Delta S = 0$ selection rule, providing direct evidence for the mixing of spin wavefunctions ($S$-mixing) induced by the comparable exchange and magneto-anisotropy energy scales within the grid. This finding highlights the potential utility of EPR for studies of exchange splittings in molecular nanomagnets, which is normally considered the sole domain of inelastic neutron scattering, thereby offering improved sensitivity and energy resolution.
قيم البحث
اقرأ أيضاً
The antiferromagnetic molecular finite chain Cr6 was studied by inelastic neutron scattering. The observed magnetic excitations at 2.6 and 4.3 meV correspond, due to the open boundaries of a finite chain, to standing spin waves. The determined energy
spectrum revealed an essentially classical spin structure. Hence, various spin-wave theories were investigated in order to assess their potential for describing the elementary excitations of finite spin systems.
X-band electron spin resonance (ESR) spectroscopy has been performed for gold nanorods (AuNRs) of four different sizes covered with a diamagnetic stabilizing component, cetyltrimethylammmonium bromide. The ESR spectra show ferromagnetic features such
as hysteresis and resonance field shift, depending on the size of the AuNRs. In addition, the ferromagnetic transition is indicated by an abrupt change in the spectra of the two smallest AuNRs studied. A large g-value in the paramagnetic region suggests that the ferromagnetism in the AuNRs originates from strong spin-orbit interaction.
We present an in-situ study of an optical lattice with tunneling and single lattice site resolution. This system provides an important step for realizing a quantum computer. The real-space images show the fluctuations of the atom number in each site.
The sub-Poissonian distribution results from the approach to the Mott insulator state, combined with the dynamics of density-dependent losses, which result from the high densities of optical lattice experiments. These losses are clear from the shape of the lattice profile. Furthermore, we find that the lattice is not in the ground state despite the momentum distribution which shows the reciprocal lattice. These effects may well be relevant for other optical lattice experiments, past and future. The lattice beams are derived from a microlens array, resulting in lattice beams which are perfectly stable relative to one another.
BaCuSi$_2$O$_6$, a $S=1/2$ quantum antiferromagnet with a double-layer structure of Cu$^{2+}$ ions in a distorted planar-rectangular coordination and with a dimerized spin singlet ground state, is studied by means of the electron paramagnetic resonan
ce technique. It is argued that multiple absorptions observed at low temperatures are intimately related to a thermally-activated spin-triplet exciton superstructure. Analysis of the angular dependence of exciton modes in BaCuSi$_2$O$_6$ allows us to accurately estimate anisotropy parameters. In addition, the temperature dependence of EPR intensity and linewidth is discussed.
Similar to nitrogen-vacancy centers in diamond and impurity atoms in silicon, interstitial gallium deep paramagnetic centers in GaAsN have been proven to have useful characteristics for the development of spintronic devices. Among other interesting p
roperties, under circularly polarized light, gallium centers in GaAsN act as spin filters that dynamically polarize free and bound electrons reaching record spin polarizations (100%). Furthermore, the recent observation of the amplification of the spin filtering effect under a Faraday configuration magnetic field has suggested that the hyperfine interaction that couples bound electrons and nuclei permits the optical manipulation of its nuclear spin polarization. Even though the mechanisms behind the nuclear spin polarization in gallium centers are fairly well understood, the origin of nuclear spin relaxation and the formation of an Overhauser-like magnetic field remain elusive. In this work we develop a model based on the master equation approach to describe the evolution of electronic and nuclear spin polarizations of gallium centers interacting with free electrons and holes. Our results are in good agreement with existing experimental observations. In regard to the nuclear spin relaxation, the roles of nuclear dipolar and quadrupolar interactions are discussed. Our findings show that, besides the hyperfine interaction, the spin relaxation mechanisms are key to understand the amplification of the spin filtering effect and the appearance of the Overhauser-like magnetic field. Based on our models results we propose an experimental protocol based on time resolved spectroscopy. It consists of a pump-probe photoluminescence scheme that would allow the detection and the tracing of the electron-nucleus flip-flops through time resolved PL measurements.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
